Product ID:W/R ENAMEL, G11507
MSDS Date:07/16/1993
FSC:8010
NIIN:00N056892
MSDS Number: CGFVX

PPG INDUSTRIES INC

4325 ROSANNA DR
ALLISON PARK, PA 15101
US

Emergency Phone: 304-843-1300

Info Phone: 412-492-5555

Cage: 4D920

PPG INDUSTRIES INC

ALLISON PARK, PA 15101 US

Telephone: 800-245-2590

Cage: 4D920

CALCIUM CARBONATE (MARBLE) (LIMESTONE)

CAS: 1317-65-3

RTECS: EV9580000

Fraction By Weight: 5-10%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST

TITANIUM OXIDE; (TITANIUM DIOXIDE)

CAS: 13463-67-7

RTECS: XR2275000

Fraction By Weight: 2-5%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST

WATER

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 10-15%

OSHA PEL N/K

ACGIH TLV: N/K

WATER; (DEIONIZED WATER)

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 30-35%

OSHA PEL N/K

ACGIH TLV: N/K

ETHANOL, 2-(2-BUTOXYETHOXY)-; (DIETHYLENE GLYCOL MONOBUTYL

CAS: 112-34-5

RTECS: KJ9100000

Fraction By Weight: 2-5%

OSHA PEL N/K

ACGIH TLV: N/K

ETHANOL, 2-DIMETHYLAMINO-; (N,N-DIMETHYL ETHANOLAMINE)

CAS: 108-01-0

RTECS: KK6125000

Fraction By Weight: 1-2%

OSHA PEL N/K

ACGIH TLV: N/K

ETHANOL, 2-BUTOXY-; (ETHYLENE GLYCOL MONOBUTYL ETHER)

CAS: 111-76-2

RTECS: KJ8575000

Fraction By Weight: 2-5%

OSHA PEL 50 PPM, S

ACGIH TLV: 25 PPM, S

FILM FORMERS ROSINS, AND ADDITIVES

Fraction By Weight: 25-30%

OSHA PEL N/K

ACGIH TLV: N/K

INVOLVED IN MANUFACTURE OF THIS PIGMENT INDICATE

RTECS: 9999999ZZ

INHAL OF TITANIUM DIOXIDE DUSTS FROM COATINGS IS

RTECS: 9999999ZZ

NO SIGNIFICANT HAZ FOR MAN. PROD CONTAINS

RTECS: 9999999ZZ

DRINKING WATER AT LOW LEVELS BY RATS FOR 30 DAYS

RTECS: 9999999ZZ

PROD CONTAINS ETHYLENE SERIES GLYCOL ETHER

RTECS: 9999999ZZ

KIDNEYS, LIVER, BLOOD &/BLOOD-FORMING TISS. THERE

RTECS: 9999999ZZ

EYE WATERING, HDCH, NAUS,

RTECS: 9999999ZZ

LEVELS ARE TOO HIGH. REDNESS, ITCH, BURNING

RTECS: 9999999ZZ

DRYNESS, ITCH, CRACKING, BURNING, REDNESS & SWELL

RTECS: 9999999ZZ

CLEARLY DEMONSTRATED DOSE-RELATED ADVERSE EFTS ON

RTECS: 9999999ZZ

ASSOC W/ADMIN OF ETHYLENE GLYCOL MONOBUTYL ETHER

RTECS: 9999999ZZ

TYPE OF AIRBORNE CONTAMINANTS AGAINST WHICH RESP

RTECS: 9999999ZZ

LEL BELOW STATED LIMIT, & TO REMOVE DECOMPOSITION

RTECS: 9999999ZZ

AND FULL LENGTH FACESHIELD .

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INGEST: HARMFUL/FATAL IF
SWALLOWED. EYE: SEV IRRIT. SKIN: PRIMARY IRRIT. MAY BE HARMFUL IF
ABSORBED THRU SKIN. INHAL: VAP & SPRAY MIST HARMFUL. VAP IRRITATES
EYES, NOSE & THROAT. RPTD EXPOS TO HIGH VAP CONCS MAY CAUSE IRRIT
OF RESP SYS & PERM BRAIN & NERV SYS DMG. INTENTIONAL MISUSE BY
(EFFECTS OF OVEREXPOSURE)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: DELIBERATELY CONC & INHALING CONTENTS
CAN BE HARMFUL/FATAL. CHRONIC: AVOID LONG TERM & RPTD CONT. PROD
EITHER CONTAINS FORMALDEHYDE/IS CAPABLE OF RELEASING FORMALDEHYDE
ABOVE 0.5 PPM UNDER C ERTAIN CNDTNS. FORMALDEHYDE IS POTENTIAL
CANCER HAZ, SKIN SENSITIZER & RESP SENSITIZER. ANIMALS INHALING
(SUP DAT)
Medical Cond Aggravated by Exposure:NOT APPLICABLE.

First Aid:INGEST: DO NOT INDUCE VOMIT. EYE: FLUSH IMMED W/PLENTY OF
WATER FOR AT LEAST 30 MIN. SKIN: FLUSH IMMED W/PLENTY OF WATER
FOLLOWED BY BY WASHING W/SOAP & WATER. INHAL: REMOVE TO FRESH AIR.
APPLY ARTF R ESP & OTHER SUPPORTIVE MEASURES AS REQUIRED. IF
INGEST, ANY TYPE OF OVEREXP/SYMPS OF OVEREXP OCCUR DURING/FOLLOWING
USE OF THIS PROD, CONT POIS CTL CTR, EMER ROOM/MED IMMED. HAVE MSDS
INFO AVAIL.

Flash Point Method:PMCC
Flash Point:200F,93C
Extinguishing Media:USE NFPA CLASS B EXTING (CARBON DIOXIDE, DRY
CHEM/UNIVERSAL AQUEOUS FILM FORMING FOAM) DESIGNED TO EXTING NFPA
(SUP DAT)
Fire Fighting Procedures:WEAR NIOSH APPRVD SCBA & FULL PROT EQUIP .
WATER SPRAY MAY BE INEFFECTIVE, BUT MAY BE USED TO COOL CLSD CONTRS
TO PVNT PRESS BUILD-UP & POSS (SUP DAT)
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE OR BURST
(DUE TO THE BUILD-UP OF STEAM PRESSURE) WHEN EXPOSED TO EXTREME
HEAT.

Spill Release Procedures:PROVIDE MAX VENT. ONLY PERS EQUIPPED W/PROPER
NIOSH APPRVD RESP & SKIN & EYE PROT SHOULD BE PERMITTED IN AREA.
REMOVE ALL SOURCES OF IGNIT. TAKE UP SPILLED MATL W/SAWDUST,
VERMICULITE/OTHER ABSORB MAT L & PLACE INTO CONTRS FOR DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DO NOT STORE ABOVE 120F. STORE LARGE
QUANTITIES IN BUILDINGS DESIGNED AND PROTECTED FOR STORAGE OF NFPA
CLASS IIIB LIQUIDS. PROTECT FROM FREEZING.
Other Precautions:IF THIS MATERIAL IS PART OF A MULTIPLE COMPONENT
SYSTEM, READ THE MSDS FOR THE OTHER COMPOMENT/COMPONENTS BEFORE
BLENDING AS THE RESULTING MIXTURE MAY HAVE THE HAZARDS OF ALL OF
ITS PARTS.

Respiratory Protection:OVEREXP TO VAPS MAY BE PREVENTED BY ENSURING
VENT CTLS, VAP EXHST/FRESH AIR ENTRY. NIOSH APPRVD (TC-23C-) AIR
PURIFYING/AIR SUPP (TC-19C-) RESPS MAY ALSO REDUCE EXPOS. READ RESP
MFR'S INSTRUCTIONS & L ITERATURE CAREFULLY TO DETERMINE(ING 20)
Ventilation:PROVIDE GEN DILUTION/LOC EXHST VENT IN VOL & PATTERN TO
KEEP CONC OF INGS BELOW LOWEST SUGGESTED EXPOS LIMITS, (ING 21)
Protective Gloves:NITRILE, NEOPRENE, LATEX.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGG (ING 22)
Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH & DELUGE
SHOWER . PROTECTIVE CLOTHING, INCLUDING IMPERMEABLE APRON.
Work Hygienic Practices:CLEAN OR DISCARD CONTAMINATED CLOTHING AND
SHOES.
Supplemental Safety and Health
EXTING MEDIA: CLASS IIIB LIQ FIRES. FIRE FIGHT PROC: AUTOIGNIT/EXPLO
WHEN EXPOSED TO EXTREME HEAT. IF WATER IS USED, FOG NOZZ ARE PREF.
HAZ DECOMP PROD: OXIDES OF NITROGEN, LEAD OXIDE, FORMALDEHYDE. E
FTS OF OVEREXP: MASSIVE QTYS OF TITANIUM DIOXIDE DUST IN LONG-TERM
STUDY DEVELOPED LUNG TUMORS. STUDIES W/HUMANS (ING 9)

Boiling Pt:B.P. Text:>149F,>65C
Vapor Pres:17.3
Vapor Density:HVR/AIR
Spec Gravity:1.13
Evaporation Rate & Reference:34 (BUTYL ACETATE=100)
Solubility in Water:55.3%
Appearance and Odor:VISCOUS LIQ W/ODOR CHARACTERISTIC OF CHEM FAMILY &
SOLVS LISTED IN ING SECTION
Percent Volatiles by Volume:63.72

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG ALKALIES, STRONG MINERAL ACIDS, OR STRONG
OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:MAY PRDCE HAZ DECOMP PRODS WHEN
HEATED. WELDING, BRAZING/FLAME-CUTTING MAY PRDCE FUMES INCL CARBON
MONOXIDE, (SUP DAT)

Waste Disposal Methods:WASTE MATERIAL MUST BE DISPOSED OF IN ACCORDANCE
WITH FEDERAL, STATE, PROVINCIAL, AND LOCAL ENVIRONMENTAL CONTROL
REGULATIONS. EMPTY CONTAINERS SHOULD BE RECYCLED OR DISPOSED OF
THROUGH AN APPROVED WA STE MANAGEMENT FACILITY.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.